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Lower thermodynamics stability of the win-NHEt adducts compared to the win-SG and win-Cys adducts (communicated elsewhere, ΔG for irreversible win-SG and win-Cys adducts are greater than 50 kcal/mol) indicates the adduct formation reaction of win with the amine to be reversible under our experimental condition

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-1%) were noted in PGZ-treated vs