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93 First, ALA is oxidized by 15-LOX-1 to form a hydroperoxide on the 13-position (13-HpOTrE), which can be rearranged by divinyl ether synthase to form an ether 92 or by hemiacetal synthase to form a hemiacetal that is spontaneously cleaved into 9( Z )-12-oxo-9-dodecenoic acid and 3( Z )-hexenal

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